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Metallofoldamers Supramolecular Architectures from Helicates to Biomimetics
Date: 24-01-2019, 14:23 | Author: creativelivenew | Favorites: |


Metallofoldamers Supramolecular Architectures from Helicates to Biomimetics
Metallofoldamers: Supramolecular Architectures from Helicates to Biomimetics By
2013 | 455 Pages | ISBN: 0470973234 | PDF | 16 MB




Metallofoldamers are oligomers that fold into three-dimensional structures in a controlled manner upon coordination with metal ions. Molecules in this class have shown an impressive ability to form single-handed helical structures and other three-dimensional architectures. Several metallofoldamers have been applied as sensors due to their selective folding when binding to a specific metal ion, while others show promise for applications as responsive materials on the basis of their ability to fold and unfold upon changes in the oxidation state of the coordinated metal ion, and as novel catalysts.Metallofoldamers: From Helicates to Biomimetic Architectures describes the variety of interactions between oligomers and metal species, with a focus on non-natural synthetic molecules.Topics covered include:the major classes of foldamers and their folding driving forcemetalloproteins and metalloenzymeshelicates: self-assembly, structure and applicationsabiotic metallo-DNAmetallo-PNA and iDNAmetallopeptidesinteractions of biomimetic oligomers with metal ionsapplications of metallofoldamersContent: Chapter 1 Metalloproteins and Metallopeptides - Natural Metallofoldamers (pages 1-50): Vasiliki Lykourinou and Li?June MingChapter 2 Introduction to Unnatural Foldamers (pages 51-89): Claudia Tomasini and Nicola CastellucciChapter 3 Self?Assembly Principles of Helicates (pages 91-123): Josef HamacekChapter 4 Structural Aspects of Helicates (pages 125-158): Martin Berg and Arne LutzenChapter 5 Helical Structures Featuring Thiolato Donors (pages 159-192): Ekkehardt Hahn and Dennis LewingChapter 6 Photophysical Properties and Applications of Lanthanoid Helicates (pages 193-248): Jean?Claude G. BunzliChapter 7 Design of Supramolecular Materials: Liquid?Crystalline Helicates (pages 249-274): Raymond ZiesselChapter 8 Helicates, Peptide?Helicates and Metal?Assisted Stabilization of Peptide Microstructures (pages 275-302): Markus AlbrechtChapter 9 Artificial DNA Directed toward Synthetic Metallofoldamers (pages 303-332): Guido H. Clever and Mitsuhiko ShionoyaChapter 10 Metal Complexes as Alternative Base Pairs or Triplets in Natural and Synthetic Nucleic Acid Structures (pages 333-377): Arnie De, Jing Kong and Catalina AchimChapter 11 Interaction of Biomimetic Oligomers with Metal Ions (pages 379-405): Galia MaayanChapter 12 Applications of Metallofoldamers (pages 407-432): Yan Zhao


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